The States of Matter

Matter is traditionally thought to exist in 4 physical states or phases. They are:

  •   Solid
  •   Liquid
  •   Gas
  •   Plasma

Each state of matter in this sequence possesses increasing amounts of energy, as reflected by the temperature ranges that they exist in.

The fundamental units of a substance consist of atoms and molecules. The 4 phases of matter represent the degree of compactness in which these units are packed and how much energy they possess. The diagram above shows how matter in one physical state can change into another phase. The relationship between these phases as a function of pressure and temperature is illustrated on a phase diagram.

 

How are the phases of matter affected by temperature and pressure?


The figure above is a phase diagram for a pure substance, as a function of temperature and pressure. Besides the main phases of solid, liquid and gas, two other areas exist - vapor and supercritical fluid. If plasma was shown, it would be on the extreme right beyond the temperatures for gases. 

A vapor is a gas existing below the substance's critical temperature (temperature at the critical point, c.p.). Below the critical temperature, a vapor can be transformed to a liquid or solid if a large enough pressure is applied to it. If the pressure and temperature both exceed those of the critical point, the distinction between gas and liquid vanishes and the substance behaves like a supercritical fluid. The vapor and supercritical fluid behavior are intermediate between those of liquids and gases.

 

How do the Characteristics of Liquid Crystal Compare and Contrast with Other Phases?  

The physical properties of a substance can be divided into macroscopic and nanoscopic behaviors.
 
 

Macroscopic Behavior
Phase Retains volume Retains Shape Compressible Flow Rate Diffusion Rate
Crystalline Solids Yes

Yes No   Slowest 

  Fastest 

 

  Slowest 

  Fastest 

 

Liquid
Crystals
Yes No No
Liquids

 

Yes No No
Gases

 

No No Yes

 
Nanoscopic Behavior

Phase

Orientational
Ordering
Translational
Ordering
Inter-molecular Forces Separation
Distance 
Crystalline Solids Yes

 

Yes   Strongest 

  Weakest 

 

  Smallest 

Largest

Liquid

Crystals

Yes No
Liquids

 

No No
Gases

 

No No

 

 

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Single Phase Diagram