Refractive index:
The index of refraction is the ratio of the
constant velocity of light in vacuum (c) to the variable
velocity of light in a transparent medium (v).
n = c / v
This property is also known as optical density
and expressed as nD20. The number 20 represent the Celsius
temperature of the sample while D represents the monochromatic
D line of the sodium spectrum (wavelength: 589.3 nm).
The consequence of this differing velocity
in different materials results in varying amount of bending
of light in different substances. Snells's law illustrates
a well-known relationship between the angle of bending and
the refractive index:
n1sin
1
= n2sin
2
The value for the index of refraction of several
materials is given below:
|
Material
|
Refractive Index
|
|
Diamond
|
2.4173
|
|
Polycarbonate polymer
|
1.6
|
|
Flint glass
|
1.575
|
|
Quartz
|
1.553
|
|
Rock salt (NaCl)
|
1.544
|
|
Hexane
|
1.3750
|
|
Ethanol
|
1.3611
|
|
Acetone
|
1.3588
|
|
Water
|
1.3328
|
|
Methanol
|
1.3288
|
|
Air
|
1.003
|
The refractive index of a substance changes
if the temperature changes or if the color of the light
used changes. Refractive index measurements can be used
to determine the concentration of a solution or ascertain
purity and identify a substance.
The nDvalue decreases as the temperature
rises. To compare experimental results with those listed
in standard tables, set at 20 degrees Celsius, the correction
is as follows:
nD20 = nDT + (T - 20)(.00045)
The temperature T is in degrees Celsius.