Why do the carbon
forms look so different?
Color is not an inherent characteristic of a
material. The color we see is depends on what kind of light
was shined on the material and how it affects that light.
A substance may:
-
transmit
-
disperse
-
reflect
-
absorb
the light at characteristic wavelengths (or frequencies) in
the spectrum (e.g. rainbow).
The interaction between light and a material depends on two
factors:
- How the atoms and molecules in a substance are arranged
structurally?
- How tightly the electrons in the substance are held by the
atoms?
If the electrons cannot absorb any energy from the light, then
the radiation passes through unmolested, so the material appears
to be transparent. However, if the electrons can rob the light
of any energy, then the light is dimmed, obscured or absorbed.
As a result, the material appears more or less opaque.
It was not known until this century why diamond and graphite,
both made from carbon atoms and possessing the same number of
electrons are optically so different. Scientists now know that
the crystalline structure of a substance determines how tightly
its electrons are held by the atoms and chemical bonds in the
material.
At the wavelengths that humans can see, light does not have
enough energy to excite the tightly held electrons in diamond,
so diamond appears transparent to us. Impurities in the diamond,
contribute electrons that can absorb light at characteristic
wavelengths, to give the diamond varying hues of color. For
example: pure diamond appears transparent, nitrogen in diamond
causes a yellow to orange tint, and boron causes a blue coloration.
Some of the electrons in graphite are loosely held, so they
can absorb and reemit (reflect) the energy of the light. The
electrons' interactions with light give graphite a metallic
luster.
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