Carbon atoms can connect to each other by forming several kinds of
chemical bonds. The different bonding schemes among the carbon atoms
can form different crystalline structures. Three of these are described
below.
Graphite:
Space Group C6/mmc C-centered hexagonal
Lattice parameters a = 2.4612 Angstroms c = 6.7079 Angstroms
Atoms/unit cell 4
Cell volume 35.189 x 10-24 cm3
X-ray density 2.2670 g/cm3
Crystalline graphite consists of sheets of carbon atoms arranged in a honeycomb
like structure with three nearest neighbors, with a C-C bond distance of
1.415 Angstroms, within the sheet. The layers are held by weak forces,
and separated by 3.35 Angstroms.
Space Group Fd3m face-centered cubic
Lattice parameters a = 3.5670 Angstroms
Atoms/unit cell 8
Cell volume 45.385 x 10-24 cm3
X-ray density 3.5155 g/cm3
The carbon atoms within diamond are arranged into a rigid, three-dimensional
network, with each atom tetrahedrally bonded to its nearest neighbors and
separated by 1.544 Angstroms.
Space Group Fm3m body-centered cubic
Lattice parameters a = 14.14 Angstroms
Atoms/unit cell 240 (4 molecules)
Cell volume 2.827 x 10-21 cm3
X-ray density 1.693 g/cm3
The carbon atoms in the Buckminster fullerenes are arranged into discrete
molecular units that are somewhat like soccer balls. These spheres are
held together by weak intermolecular forces to form a cubic structure.
Click here to find out how to calculate the
density of a crystal using these data.
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